Edited H2BC program Nils T. Nyberg, Jens Ø. Duus, Ole W. Sørensen J. Am. Chem. Soc. 127, 6154-6155 (2005) MRC, 2005 Echo/Antiecho gradient selection uses a 3rd order low-pass J-filter for suppression of one-bond correlations Using decoupler channel 1 for X-pulses Flags: presat y: presaturation during relaxation delay n: no presaturation during relaxation delay edit y: up/down spectrum n: standard H2BC Pulses and Powers: pw 90 degrees transmitter pwx 90 degrees decoupler 1 pwlvl 90 degrees transmitter hard pulse power level pwxlvl power level for decoupler high power tpwr transmitter high power level satpwr power level for saturation of solvent signal using transmitter during relaxation delay satdly duration of presaturation satfrq presaturation offset hpdseq composite pulse decoupling (CPD) program for heteronuclear decoupling during T (GARP, CHIRP, etc) optimise for 1Jxh hpdmf dmf for decoupling during T hpdpwr decoupler power for decoupling during T NB: For optimal results make sure that the sequence used here sets the fine attentuation internally! See Pandora's Box manuals for more details. The same is true of the sequence used for dseq hpdres angle resolution for hpdseq dseq etc: optimise for nJxh where n>1. i.e. use a lower power decoupling so you can acquire more points Coupling constants Jmin smallest 1J(XH) for LPJF setting Jmax largest 1J(XH) for LPJF setting Jxh optimal 1J(XH) for editing set to the average of Jmin and Jmax. You can however, alter this value if for instance you have one or two carbons with radically different 1J(CH) and you don't mind having more crosstalk for these. In this case set to the average of the 1J(CH)s of the rest of the spectrum Delays BigT Constant time evolution period between 18-25 msec Gradient settings gt1 length of the gradients used ca. 1msec gzlvl1 max size of gradients. gstab gradient recovery delay Other settings array='edit,phase' (for processing with VNMR ) Processing: A: wft2d(1,0,-1,0,1,0,-1,0,0,-1,0,-1,0,-1,0,-1) B: wft2d(1,0,-1,0,-1,0,1,0,0,-1,0,-1,0,1,0,1) Version History: Version 1: Initial release 08/02/06 by Dr. A.J. Benie Testing Information: vnmr61C:Inova 500:Solaris acquisition host (Works OK) edit line 160 to change psg_abort(1) to abort(1) vnmrJ1.1D:Inova 800:Solaris acquisition host (Works OK) vnmrJ1.1D:n/a:Linux data station (compiles and displays OK) Disclaimer: This pulse program has been tested and found to be working on our spectrometers, but adjustments in pulse program syntax and/or parameter sets may be necessary for other hardware configurations or systems. Please pay attention to the requirements of your system, when implementing this pulse program. The Carlsberg Laboratory or the Instrument Center does not make any warranties with respect to this software. In no event will Carlsberg Laboratory or the Instrument Center be liable for any loss, damages of any nature arising or relating to the use or performance of this software.